HL1, BlueShift, Opposing Force, HL2, HL2:E1, HL2:E2
I personally say play Blueshift first, then Opposing Force. Opposing Force was released before Blueshift, but Blueshift takes place in the game before Opposing Force(both take place parallel to the HL1 timeline, Blueshift going from before the beginning of HL1 to when Gordon gets knocked out at the midway point in HL1, Opposing Force starts sometime around thereabouts, and lasts past when Gordon leaves for Xen), plus Blueshift uses only the items that HL1 uses, while Opposing Force adds in a bunch of new items and gameplay mechanics.
Play decay when you find a decent person to play with, let me know if you need help setting up a server so that you can play with people online. Playing a lan game is easy, but an internet game takes some work to set up.
Also, you’ve got HL1, and HL2 with the episodes, you should be moving on top MODS. Like They Hunger Trilogy(HL1), and Minerva: Metastasis(HL2), The Trap(HL1), Research and Development(HL2:e2), Sweet Half Life(HL1), USS Darkstar(HL1), Point of View(HL1), and Offshore(HL2:e2)